Named Reactions and Syntheses from the Literature.
Perused by Members of the Kiessling Group.
Weekly and Weakly.
Friday, February 27, 2009
Eschenmoser Methenylation
The introduction of a (dimethylamino)methyl group into the alpha-position of a carbonyl group using dimethyl(methylene)ammonium iodide (Eschenmoser's salt), followed by an elimination to the corresponding alpha-methylene carbonyl compound.
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