The skeletal rearrangement of alpha-halo ketones, with no hydrogen atom at the alpha'-position or bicyclic alpha-halo ketones with an alpha'-hydrogen atom at the bridgehead carbon atom, upon treatment with a nucleophile.
The [4 + 3]-Cycloaddition/Quasi-Favorskii Process. Synthesis of the Carbocyclic Core of Tricycloclavulone
Michael Harmata and Sumrit Wacharasindhu
Org. Lett., 2005, 7 (13), pp 2563–2565
DOI: 10.1021/ol050598l
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